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Understanding SN1 Mechanism in Chemistry

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Created December 8, 2025

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If SN2 is a group attack, SN1 is a solo mission — and the first step is the molecule

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straight-up leaving. SN1 stands for Substitution Nucleophilic Unimolecular, and the key word here is unimolecular.

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That means the rate depends on only ONE thing: the substrate. Step one is the slow,

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rate-determining step. The leaving group leaves first, forming a carbocation.

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Because carbocations are unstable, SN1 only works when they’re stabilized. That’s why tertiary

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carbons are best, secondary sometimes works, and primary basically never does.

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Once the carbocation forms, anything nearby can attack — the nucleophile jumps

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in after the hard part is over. Now here’s the super testable detail: Carbocations are

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