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Understanding VSEPR Theory in Chemistry

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Created October 29, 2025

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VSEPR (Valence Shell Electron Pair Repulsion) theory is a model used in chemistry to predict the three-dimensional

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shape (molecular geometry) of molecules based on the principle that electron pairs in the valence shell

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of a central atom will arrange themselves to be as far apart as possible to minimize repulsion.

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To use the theory, one must first draw the Lewis structure, then count the total number of electron

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groups (both bonding pairs and lone pairs) around the central atom, and finally,

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use this information to determine the electron-group geometry and the resulting molecular geometry.

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